Product ID:BLUE SUPER-SPOT, E&I 23 24
MSDS Date:01/22/1996
FSC:8010
NIIN:00N078830
MSDS Number: CGYNM

NELSON PAINT CO OF MICHIGAN INC

KINGSFORD, MI 49802-2040
US

Emergency Phone: 800-255-3924

Info Phone: 906-774-5566

Preparer: DOYLE YODER

Cage: 17833

NELSON PAINT CO OF MICHIGAN INC

2040 KINGSFORD, MI 49802-2040 US

Telephone: 906-774-5566

Cage: 17833

METHANOL; (METHYL ALCOHOL) (SARA 313) (CERCLA)

CAS: 67-56-1

RTECS: PC1400000

Fraction By Weight: <15%

OSHA PEL 200 PPM, S

ACGIH TLV: 200 PPM; 250 STEL, S

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

STODDARD SOLVENT; (ALIPHATIC HYDROCARBONS)

CAS: 8052-41-3

RTECS: WJ8925000

Fraction By Weight: <35%

OSHA PEL 500 PPM

ACGIH TLV: 100 PPM

CNTNRS TO HEAT, FLAME, SPKS, STATIC ELEC OR OTHER

RTECS: 9999999ZZ

DEATH. EMPTY DRUMS SHOULD BE COMPLETELY DRAINED,

RTECS: 9999999ZZ

OR PROPERLY DISPOSED OF. KEEP CNTNRS TIGHTLY CLOSED.

RTECS: 9999999ZZ

CLOSED CNTNRS MAY EXPLODE WHEN EXPOSED TO EXTREME

RTECS: 9999999ZZ

SYSTEM DMG. INTENTIONAL MISUSE BY

RTECS: 9999999ZZ

METHANOL WHICH CAN CAUSE INTOXICATION & CNS

RTECS: 9999999ZZ

FORMALDEHYDE. THESE METABOLITES CAN CAUSE METABOLIC

RTECS: 9999999ZZ

METABOLISM IS REQD FOR THESE TOX SYMPS, THEIR ONSET

RTECS: 9999999ZZ

ETHANOL COMPETES FOR SAME METABOLIC PATHWAY & HAS

RTECS: 9999999ZZ

IS INDICATED IN SYMPTOMATIC PATIENTS OR AT METHANOL

RTECS: 9999999ZZ

BY HEMODIALYSIS. KEEP WARM, QUIET & GET IMMED MED

RTECS: 9999999ZZ

LUNGS FROM VOMIT CAN CAUSE CHEM PNEUMIT WHICH CAN

RTECS: 9999999ZZ

AVOID RUNOFF INTO STORM SEWERS AND DITCHES

RTECS: 9999999ZZ

USE NIOSH APPRVD POS PRESS AIR SUPPLIED RESP IF

RTECS: 9999999ZZ

EXPOS LEVELS ARE NOT KNOWN OR ANY OTHER

RTECS: 9999999ZZ

ALL HAZARD PRECS GIVEN IN DATA SHEET MUST BE

RTECS: 9999999ZZ

REMOVE CONTAMD CLTHG & WASH BEFORE REUSE. USE ONLY

RTECS: 9999999ZZ

TRANSFERRING MATL. USE SPARK-PROOF TOOLS &

RTECS: 9999999ZZ

AVOID BRTHG VAPORS FROM HEATED MATL. AVOID CONTACT

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYE CONTACT: LIQ, AEROSOLS & VAPS OF
PROD ARE IRRITATING & CAN CAUSE PAIN, TEARING, REDDENING & SWELL
ACCOMPANIED BY STINGING SENSATION &/OR FEELING LIKE THAT OF FINE
DUST IN EYES. SKIN CONTACT: PRLNG D/RPTD CONTACT CAN RSLT IN DEFAT
& DRYING OF SKIN WHICH MAY RSLT IN SKIN IRRIT & DERM (RASH). INHAL:
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: HDCHS, DIZZ, NAUS, DECRD BLOOD PRESS,
CHGS IN HEART RATE & CYANOSIS (CHARACT BY BLUISH DISCOLORATION OF
SKIN & NAILS) MAY RSLT FROM OVEREXP TO VAP OR SKIN EXPOS. INGEST:
THIS MATL MAY BE HAR MFUL/FATAL IF SWALLOWED. CHRONIC: REPORTS HAVE
ASSOC RPTD & PRLNGD OCCUP OVEREXP TO SOLVS W/PERM BRAIN & NERVOUS
(ING 8)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYES: IMMED FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MIN. GET
IMMED MED ATTN. SKIN: IMMED FLUSH SKIN W/PLENTY OF WATER. WASH
W/SOAP & WATER. REMOVE SOILED CLTHG. WASH CLTHG SEPARATELY BEFORE
REUSE. GET MED ATTN IF IRRIT DEVELOPS OR PERSISTS. INHAL: REMOVE
TO FRESH AIR. IF NOT BRTHG, GIVE ARTF RESP. IF BRTHG IS DFCLT, GIVE
OXYGEN. GET IMMED MED ATTN. INGEST: NOTE TO MD: THIS PROD CONTAINS
(ING 9)

Flash Point:72.0F,22.2C
Lower Limits:1.0%
Upper Limits:36.0%
Extinguishing Media:ALCOHOL FOAM, CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP .
CNTNRS CAN BUILD UP PRESS IF EXPOSED TO HEAT (FIRE). WATER RUNOFF
CAN CAUSE ENVIRONMENTAL DAMAGE. DIKE (SUPDAT)
Unusual Fire/Explosion Hazard:AVOID BRTHG DUSTS & FUMES FROM BURNING
MATL. VAPS MAY FORM EXPLO MIX W/AIR. VAPS CAN TRAVEL TO A SOURCE OF
IGNIT & FLASH BACK. "EMPTY" CNTNRS RETAIN (SUPDAT)

Spill Release Procedures:EVACUATE ALL NON-ESSNTL PERS. REMOVE ALL
SOURCES OF IGNIT. VENT AREA. EQUIP EMPLOYEES W/APPROP PROT EQUIP.
DIKE AROUND SPILLED MATL. COVER SPILL W/ABSORB MATL & SHOVEL WITH
NON-SPARKING TOOLS INTO CNT NR. REMOVE CNTNRS TO SAFE AREA & SEAL.
(ING 16)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE AWAY FROM INCOMPATIBLE
SUBSTANCES. WASH THOROUGHLY AFTER HANDLING. KEEP AWAY FROM HEAT,
SPARKS & FLAME. KEEP CONTAINER CLOSED WHEN NOT IN USE.
Other Precautions:DO NOT INHALE MIST OR VAPOR. KEEP OUT OF REACH OF
CHILDREN. APPLY WITH BACK TO WIND DURING OUTDOOR APPLICATION. DO
NOT WEAR CONTACT LENSES.

Respiratory Protection:NIOSH APPRVD AIR PURIFYING RESP W/ORGANIC VAPOR
CARTRIDGE OR CANISTER MAY BE PERMISSIBLE UNDER CERTAIN
CIRCUMSTANCES WHERE AIRBORNE CONCS ARE EXPECTED TO EXCEED EXPOS
LIMS. PROTECTION PROVIDED BY AIR PURIFYING RESPS IS LIMITED. (ING
17)
Ventilation:LOCAL EXHAUST VENTILATION MAY BE NECESSARY TO CONTROL ANY
AIR CONTAMINANTS TO WITHIN THEIR TLVS DURING USE OF PRODUCT.
Protective Gloves:CHEMICAL RESISTANT GLOVES.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER .
WHERE CONTACT IS LIKELY, WEAR CHEMICAL SUIT & RUBBER BOOTS.
Work Hygienic Practices:CNTNRS OF THIS MATL MAY BE HAZ WHEN EMPTIED.
SINCE EMPTIED CNTNRS RETAIN PROD RESIDUES (VAP, LIQ, &/OR SOLID),
(ING 19)
Supplemental Safety and Health
FIRE FIGHT PROC: & COLLECT WATER USED TO FIGHT FIRE. WATER SPRAY MAY BE
USED FOR COOLING CNTNRS TO PVNT POSS PRESS BUILD-UP & AUTO-IGNIT OR
EXPLO WHEN EXPOSED TO EXTREME HEAT. EXPLO HAZ: PROD RESIDUE (LIQ
&/OR VAP) & CAN BE DANGEROUS. DO NOT PRESSURIZE, CUT, WELD, BRAZE,
SOLDER, DRILL, GRIND OR EXPOSE SUCH (ING 4)

Boiling Pt:B.P. Text:>147F,>64C
Vapor Density:HVR/AIR
Spec Gravity:1.0372
VOC Grams/Liter:5.19
Evaporation Rate & Reference:FASTER THAN BUTYL ACETATE
Solubility in Water:PARTIAL
Appearance and Odor:BLUE LIQUID; SLIGHT SOLVENT ODOR.
Percent Volatiles by Volume:85.3

Stability Indicator/Materials to Avoid:YES
AVOID CONTACT WITH STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:HEAT, SPARKS AND OPEN FLAMES.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE AND
NO*X.

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND
FEDERAL LAWS. DO NOT DISCHARGE INTO WATERWAYS WITHOUT PROPER
AUTHORITY.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.